(1S,4R)-4,7,7-trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride - Names and Identifiers
Name | (-)-(1S,4R)-Camphanoyl Chloride
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Synonyms | (-)-CAMPHANIC CHLORIDE (-)-CAMPHANIC ACID CHLORIDE (-)-Camphanic acid chloride (1S)-(-)-Camphanicacidchloride (1S,4R)-(-)-Camphanic chloride (-)-(1S,4R)-Camphanoyl Chloride 3-oxa-2-oxobornane-4-carbonyl chloride 4,7,7-trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride (1S)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chlorid (1S,4R)-4,7,7-trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride
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CAS | 39637-74-6
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EINECS | 254-552-4 |
InChI | InChI=1/C10H13ClO3/c1-8(2)9(3)4-5-10(8,6(11)12)14-7(9)13/h4-5H2,1-3H3 |
InChIKey | PAXWODJTHKJQDZ-RGURZIINSA-N |
(1S,4R)-4,7,7-trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride - Physico-chemical Properties
Molecular Formula | C10H13ClO3
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Molar Mass | 216.66 |
Density | 1.2072 (rough estimate) |
Melting Point | 71-73°C(lit.) |
Boling Point | 310.92°C (rough estimate) |
Specific Rotation(α) | -18 º (c=2, CCl4) |
Flash Point | 125°C |
Water Solubility | decomposes |
Vapor Presure | 0.00119mmHg at 25°C |
Appearance | Powder |
Color | Yellow to orange-brown |
BRN | 3590860 |
Storage Condition | 2-8°C |
Sensitive | Moisture Sensitive |
Refractive Index | 1.5390 (estimate) |
MDL | MFCD00135626 |
(1S,4R)-4,7,7-trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride - Risk and Safety
Risk Codes | R34 - Causes burns
R29 - Contact with water liberates toxic gas
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Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S8 - Keep container dry.
S27 - Take off immediately all contaminated clothing.
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UN IDs | UN 3261 8/PG 2 |
WGK Germany | 3 |
FLUKA BRAND F CODES | 10-21 |
HS Code | 29322090 |
Hazard Class | 8 |
Packing Group | II |
(1S,4R)-4,7,7-trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride - Introduction
(-)-(1S,4R)-Camphanoyl Chloride, also known as (-)-(1S,4R)-Camphanoyl Chloride, is an organic compound. Its chemical formula is C10H13ClO and its molecular weight is 182.66. It is solid and has a pungent smell.
(-)-(1S,4R)-Camphanoyl Chloride have a variety of applications. First of all, it is an important reagent in organic synthesis and can be used to synthesize a variety of organic compounds, such as drugs, fragrances and rubber additives. Secondly, it is often used as a catalyst, especially in chiral catalytic reactions, which can effectively catalyze the synthesis of chiral compounds.
The method for preparing (-)-(1S,4R)-Camphanoyl Chloride is mainly obtained by reacting (-)-(1S,4R)-cantanone with thionyl chloride. The reaction conditions are generally room temperature, and it is desirable to control the pH and temperature of the reaction.
Regarding safety information,(-)-(1S,4R)-Camphanoyl Chloride is an irritating compound. Contact with skin and eyes may cause irritation and burns. During use, it is recommended to wear appropriate protective gloves and glasses, and ensure that you operate in a well-ventilated environment. In addition, it should be stored in a cool, dry place, separate from oxidants and strong acids, and avoid high temperatures and fire sources. If inhaled or ingested, seek medical attention immediately.
Last Update:2024-04-09 20:52:54